Nonadditive hard-sphere fluid mixtures: a simple analytical theory.

نویسندگان

  • Riccardo Fantoni
  • Andrés Santos
چکیده

We construct a nonperturbative fully analytical approximation for the thermodynamics and the structure of nonadditive hard-sphere fluid mixtures. The method essentially lies in a heuristic extension of the Percus-Yevick solution for additive hard spheres. Extensive comparison with Monte Carlo simulation data shows a generally good agreement, especially in the case of like-like radial distribution functions.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Theory of asymmetric nonadditive binary hard-sphere mixtures.

It is shown that the formal procedure of integrating out the degrees of freedom of the small spheres in a binary hard-sphere mixture works equally well for nonadditive as it does for additive mixtures. For highly asymmetric mixtures (small size ratios) the resulting effective Hamiltonian of the one-component fluid of big spheres, which consists of an infinite number of many-body interactions, s...

متن کامل

Multicomponent fluid of nonadditive hard spheres near a wall.

A recently proposed rational-function approximation [Phys. Rev. E 84, 041201 (2011)] for the structural properties of nonadditive hard spheres is applied to evaluate analytically (in Laplace space) the local density profiles of multicomponent nonadditive hard-sphere mixtures near a planar nonadditive hard wall. The theory is assessed by comparison with NVT Monte Carlo simulations of binary mixt...

متن کامل

Fundamental measure density functional theory for nonadditive hard-core mixtures: the one-dimensional case.

We treat a one-dimensional binary mixture of hard-core particles that possess nonadditive diameters. For this model, a density functional theory is constructed following similar principles as an earlier extension of Rosenfeld's fundamental measure theory to three-dimensional nonadditive hard-sphere mixtures. The theory applies to arbitrary positive and moderate negative nonadditivity and reduce...

متن کامل

Bridging and depletion mechanisms in colloid-colloid effective interactions: A reentrant phase diagram.

A general class of nonadditive sticky-hard-sphere binary mixtures, where small and large spheres represent the solvent and the solute, respectively, is introduced. The solute-solute and solvent-solvent interactions are of hard-sphere type, while the solute-solvent interactions are of sticky-hard-sphere type with tunable degrees of size nonadditivity and stickiness. Two particular and complement...

متن کامل

Crystallization and phase separation in nonadditive binary hard-sphere mixtures

We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review. E, Statistical, nonlinear, and soft matter physics

دوره 84 4 Pt 1  شماره 

صفحات  -

تاریخ انتشار 2011